Bond Type Generally Formed Between Bond Formed By Properties Associated with bond type Example of substances Utilizing bonf type
Covalent Atoms of non-metallic elements of similar electronegativity Sharing of electron pairs Stable non ionizing molecules-not conductors of electricity in any ohase C2 H5
Ionic Atoms of metallic and non-metallic elements of wide.y different electronegativities Elec. attraction between ions resulting from transfer of electrons fron one to another Charged ions in gas liwuid and soid. Sokid is electrically non- sonducting. Gas and liquid are condustors NaCl, K2 O, BaS, LiH
Metallic Atoms of metallic elements Common exchange of outer electrons between atons of low electronegativity Electrical conductors in all ohases, luster Na, Au, Cu. Zn
Dipole Polar covalent molecules Electrical attraction between dioples resulting from polar bonds Substances have higher boiling and melting points than those having non-polar molesules of similar size ICl, SO2
Hydrogen Molecules having hydrogen attached to atim of high electronegativity Attraction of exposed proton to electronegative atom in neigh boring molecule substances have mush higher boiling and melting points than those having non-polar molecules of similar size H2 O, HF
Dispersion Forces Non polar molecules Weak electrical fluctuations which destroy spherical symmetry of electronic fields about atoms Substanve have soft crustals and comparaticeley low melting and boiling points He, Ar, Cl2 ,CH4
Special covalent
NETWORK CRYSTAL - carbon, silicon - HIGH m.p. S1 C2 , C, S1 O2
substance Melting Point () Boiling point () Reason
C2 2700 - Networl Crystal
Au 1063 2807 Metallic
NaF 988 1695 Ionic
NaI NaOH 651 318 1300(May Decompose) 1300(may Decompose) Electronegativity
H2 O 0 100 Hydrogen Bonding
HI HBr -50 -88 -35(Dipolar) -65(Dipolar) Molar Mass
Ne He -248 -272 -246(London) -269(london) Molar Mass
Except N->Ne
The above are general nrules which are useful BUT there are exceptions.
Nonpolar molecules like CH4 , CCl4 , etc are placed with the London forces because of their shapes, they are nonpolar and have no dipolar forces. As the molar mass increases, so does the attraction (easier to induce a dipole) therefore their melting points also tend to rise.
Pridict the type of conding that is displayed in the following substances
Xe London
ICl Dipolar
CO2 London
HF H.B.
NaBr Ionic
HI Dipolar
CH4 London
CO Dipolar
S1 O4 Network Crystal
diamond (C) Network Crystal
CH3 Cl
CaCO3 Ionic
O2 London
NH3 Hydrogen
N2 H6 Hydrogen Bonding
CS2 London
H2 O Hydrogen Bonding
Fe Metallic
Pt Metallic
SO2
F2 London
SuO2 Network
H2 O2 Hidrogen Bonding
CCl4 London
VSEPRT (Valence shell electron pair repulsion)
Basic Shapes :
1. Collinear (linear triatomic)
2. Traiangular Planar
3. Tetrahedral
4. Triangular Pyramidal
5. Angular